(Dimethyl­formamide-κO){4,4′,6,6′-tetra­bromo-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ4 O,N,N′,O′}copper(II) dimethyl­formamide solvate

نویسندگان

  • Yu Wu
  • Bin Xie
  • Li-Ke Zou
  • Wei-Ping Wu
  • Lu Lu
چکیده

In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetra-dentate Schiff base ligand and the O atom of one dimethyl-formamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethyl-formamide solvent mol-ecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0.259 (4). The crystal packing is stabilized by C-H⋯O inter-actions.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate

In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord-inated in a square-planar geometry by two N atoms and two O atoms of the 6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl--idyne)]diphenolate ligand. The Na(I) ion is hexa-coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the wa...

متن کامل

Bis{μ-4,4′,6,6′-tetra­bromo-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]­diphenol­ato}­bis­[(dimethyl­formamide)cadmium(II)]

The Schiff base ligand derived from the condensation of 3,5-dibromo-salicylaldehyde and 1,2-phenyl-enediamine, in the presence of dimethyl-formamide, forms the centrosymmetric title neutral binuclear distorted complex, [Cd(2)(C(20)H(10)Br(4)N(2)O(2))(2)(C(3)H(7)NO)(2)], with the two octa-hedral Cd atoms linked by two O atoms. All bond lengths and angles show normal values.

متن کامل

Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate

In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa-hedral geometry by the four O atoms of the diphenola...

متن کامل

The cocrystal aqua­chlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ4 O,N,N′,O′}­manganese(III)–chlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ4 O,N,N′,O′}(methanol-κO)manganese(III) (1/1)

The asymmetric unit of the title complex, [Mn(C(28)H(30)N(2)O(2))Cl(H(2)O)][Mn(C(28)H(30)N(2)O(2))Cl(CH(3)OH)], contains two discrete Mn(III) complexes of a Schiff base ligand, with an N(2)O(2) donor set. Both Mn(III) centers are in a distorted octa-hedral geometry with the N(2)O(2) donor atoms of the tetra-dentate Schiff base dianion in the equatorial plane. The axial positions in the coordina...

متن کامل

{4,4′,6,6′-Tetra­chloro-2,2′-[(spiro­[4.4]nonane-1,6-di­yl)bis­(nitrilo­methyl­idyne)]diphenolato-κ4 O,N,N′,O′}nickel(II)

The title compound, [Ni(C(23)H(20)Cl(4)N(2)O(2))], has an Ni(II) ion in a square-planar coordination formed by two imine N and two phenolato O atoms.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009